Preheat the oven to 350°F. Line a muffin pan with 12 cupcake liners and set aside.
Put the cocoa powder, instant coffee (or espresso powder) and boiling water into a small bowl and whisk until a smooth paste forms then set aside to cool.
½ cup dutch processed cocoa powder, 1 teaspoon instant coffee, ½ cup boiling water
In a large mixing bowl, add the eggs, sugar, vegetable oil, buttermilk and vanilla extract. Whisk until completely combined (1-2 minutes).
2 large eggs, 1¼ cups granulated sugar, ⅓ cup vegetable oil, ½ cup buttermilk, 2 teaspoons vanilla extract
To the bowl, add the cooled chocolate paste and whisk again until completely combined.
Sift in the flour, baking soda, baking powder and salt then use a rubber spatula to gently fold the dry ingredients into the wet ingredients. The mixture will look very runny and that is fine.
1 cup all purpose flour, ½ teaspoon baking soda, ½ teaspoon baking powder, ½ teaspoon salt
Divide the cupcake batter between the cupcake liners. They will be around 3/4 full.
Put the cupcakes into the center of the preheated oven and bake for 18 minutes or until the cupcakes spring back when touched with your finger and a toothpick inserted into the middle comes out clean.
Leave the cupcakes in the muffin pan for 5 minutes then transfer to a wire rack to completely cool.